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Question

The correct reactants for the preaparation of boranes is:

A
reaction of borides with phosphoric acid
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B
reaction of boron trichlorides with phosphoric acid
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C
reaction of borides with phosphorous acid
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D
reaction of boron trichlorides with phosphorous acid
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Solution

The correct option is A reaction of borides with phosphoric acid
Boranes are prepared by reaction of a solid borohydride (i.e., a saltcontaining the BH4 ion) with an anhydrous acid,
2NaBH4+2H3PO4B2H6+2NaH2P4+2H2


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