The correct sequence of bond enthalpy of ′C—X′ bond is :
A
CH3–Cl>CH3–F>CH3–Br>CH3–l
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B
CH3–F<CH3–Cl<CH3–Br<CH3–l
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C
CH3–F>CH3–Cl>CH3–Br>CH3–l
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D
CH3–F<CH3–Cl>CH3–Br>CH3–l
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Solution
The correct option is CCH3–F>CH3–Cl>CH3–Br>CH3–l The size of halogen atom increases from FtoI hence bond length from C–FtoC–I increases due to decrease of effective nuclear charges on electrons. ∴ Bond enthalpy from CH3–FtoCH3–I decreases. ∙ So Correct Answer is option (c)