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Question

The correct sequence of bond enthalpy of C−X bond is

A
CH3F<CH3Cl<CH3Br<CH3I
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B
CH3F>CH3Cl>CH3Br>CH3I
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C
CH3F<CH3Cl>CH3Br>CH3I
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D
CH3Cl>CH3F>CH3Br>CH3I
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Solution

The correct option is B CH3F>CH3Cl>CH3Br>CH3I
Bond enthalpy is inversely proportional to the bond length.
Larger the bond length, smaller is the energy required to break the bond. The bond length order of CX bond in methyl halides depends on the size of the halogen atom.
The size of halogen atom increases from F to I hence bond length increase from CF to CI.
Thus, the correct order of bond enthalpy is
CH3F>CH3Cl>CH3Br>CH3I

Hence, option (B) is the correct answer.


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