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Question

The correct sequence of bond enthalpy of CX bond is :

A
CH3Cl>CH3F>CH3Br>CH3l
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B
CH3F<CH3Cl<CH3Br<CH3l
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C
CH3F>CH3Cl>CH3Br>CH3l
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D
CH3F<CH3Cl>CH3Br>CH3l
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Solution

The correct option is C CH3F>CH3Cl>CH3Br>CH3l
The size of halogen atom increases from F to I hence bond length from CF to CI increases due to decrease of effective nuclear charges on electrons.
Bond enthalpy from CH3F to CH3I decreases.
So Correct Answer is option (c)
CX Bond Bond dissociation enthalpies/ kJ mol1
CH3F

CH3Cl

CH3Br

CH3l
452

351

293

234

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