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Question

The correct sequence of relationships between the compounds of pairs (i) - (iv) respectively is:


A
Identical, enantiomers, diastereomers and structural isomers
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B
Enantiomers, identical, structural isomers and diastereomers
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C
Enantiomers, identical, diastereomers and structural isomers
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D
Identical, identical, diastereomers and structural isomers
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Solution

The correct option is C Enantiomers, identical, diastereomers and structural isomers

(i) Enantiomers are the stereoisomers which are non-superimposable mirror images of each other. Enantiomers have opposite configurations at the respective asymmetric centre.


(ii) These molecules have the same configuration. So, they are identical.


(iii) Diastereoisomers are non-identical non-mirror images of each other having the same bonding sequence. They arise when two or more non-mirror stereisomers of a compound have different configurations at one or more (not all) of the respective stereocentres.


(iv) Structural isomers have different connectivity of atoms/species.

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