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Question

The correct sequence of steps involved in the mechanism of Cannizzaro's reaction is:

A
nucleophilic attack, transfer of H and transfer of H+
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B
transfer of H, transfer of H+ and nucleophilic attack
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C
transfer of H+, nucleophilic attack and transfer of H
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D
electrophilic attack by OH, transfer of H+ and transfer of H
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Solution

The correct option is A nucleophilic attack, transfer of H and transfer of H+

The Cannizzaro reaction is as:
HCHO+HCHOKOH(50%)−−−−−−CH3OHmethylalcohol+HCOOK+acetate

The mechanism of Cannizzaro reaction is as:

Step I: Attack of nucleophile OH to the carbonyl carbon

Step II: The transfer of hydride ion from anion (I) to the second molecule of aldehyde and finally rapid transfer of proton takes place.

Option A is correct.

680803_639975_ans_61e9d1f9f2e240e5b5fcbd0593667495.PNG

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