The correct option is B 3,0,0,12
The correct set of four quantum numbers for the outermost electron of sodium (Z=11) is 3,0,0,12
The electronic configuration of Na is 1s22s22p63s1. Thus, the last electron is in 3s sub-shell.
For 3s sub-shell, n=3,
l=0, m=0 and s=±12