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Question

The correct set of products obtained in the following reactions
RCNreduction−−−−−→(A), RCN(i)CH3MgBr−−−−−−−−→(ii)H2O(B), RNChydrolysis−−−−−−→(C), RNH2HNO2−−−−→(D)
The answer is:

A
(A):2o Amine; (B): Methyl ketone; (C):1o Amine; (D) Alcohol
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B
(A):1o Amine; (B): Methyl ketone; (C):1o Amine; (D) Alcohol
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C
(A):2o Amine; (B): Methyl ketone; (C):2o Amine; (D) Acid
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D
(A):2o Amine; (B): Methyl ketone; (C):2o Amine; (D) Aldehyde
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Solution

The correct option is B (A):1o Amine; (B): Methyl ketone; (C):1o Amine; (D) Alcohol
The compound (A) is a primary amine:
RCNreduction−−−−RNH2(A)

The compound (B) is a methyl ketone:
RCN(i)CH3MgBr−−−−−−−(ii)H2ORCOCH3(B)

The compound (C) is a primary amine:
RNChydrolysis−−−−−RNH2(C)

The compound (D) is an alcohol:
RNH2HNO2−−−ROH(D)

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