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Question

The correct statement(s) about O3 is(are):


A

O−O bond lengths are equal

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B

Thermal decomposition of O3 is endothermic

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C

O3 is diamagnetic in nature

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D

O3 has a bent structure

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Solution

The correct options are
A

O−O bond lengths are equal


B

Thermal decomposition of O3 is endothermic


C

O3 is diamagnetic in nature


D

O3 has a bent structure


Ozone has two resonance structures and the central oxygen atom always has a single bond with one oxygen and a double bond with the other terminal oxygen atom. Both contributors are equivalent and in practice, the spectroscopic data reveals that all the bonds are equal in length – much like what we would expect from a resonance hybrid.

Unlike O2,O3 has all electrons paired and hence it is diamagnetic.
As you can see, it features a bent structure. What about the decomposition of Ozone to oxygen?
Also, decomposition of ozone is exothermic.
2O32O2+68 kCal

Hence, all the options are correct.


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