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Byju's Answer
Standard XII
Chemistry
Spontaneity
The correct t...
Question
The correct thermodynamic conditions for the spontaneous reaction at all temperatures is : (a) ∆H<0 and ∆S < 0 (b) ∆H < 0 and ∆S <0 (c) ∆H <0 and ∆S = 0 (d) ∆H >0 and ∆S < 0 Reaction is spontaneous when ∆S is positive and ∆H is negative
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Similar questions
Q.
Predict whether the reaction
C
O
(
g
)
+
(
1
2
)
O
2
(
g
)
→
C
O
2
(
g
)
at 300 K is spontaneous & exothermic or non-spontaneous & endothermic, when the standard entropy change is
−
0.094
k
J
m
o
l
−
1
K
−
1
.
The standard Gibb's free energies of formation for
C
O
2
and
C
O
are
−
394.4
a
n
d
−
137.2
k
J
m
o
l
−
1
respectively.
Q.
Assertion :If both
Δ
H
0
and
Δ
S
0
are positive then reaction will be spontaneous at high temperature. Reason: All processes with positive entropy change are spontaneous.
Q.
For a non-spontaneous reaction, at 30
0
C,
Δ
H>0
&
Δ
S > 0. The reaction becomes spontaneous,elta
by
Q.
For a particular reaction,
Δ
H
o
=
−
33.9
k
J
a
n
d
Δ
S
o
=
−
113
J
K
−
1
m
o
l
−
1
. This reaction is:
Q.
A change in the free energy of a system at constant temperature and pressure will be:
Δ
s
y
s
G
=
Δ
s
y
s
H
−
T
Δ
s
y
s
S
At constant temperature and pressure,
Δ
s
y
s
G
<
0
(
s
p
o
n
t
a
n
e
o
u
s
)
Δ
s
y
s
G
=
0
(
e
q
u
i
l
i
b
r
i
u
m
)
Δ
s
y
s
G
>
0
(
n
o
n
−
s
p
o
n
t
a
n
e
o
u
s
)
If both
Δ
H
and
Δ
S
are negative, the reaction will be spontaneous:
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