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Question

The covalent alkaline earth metal halide (X=Cl, Br, I) is

A
SrX2
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B
CaX2
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C
MgX2
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D
BeX2
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Solution

The correct option is D BeX2
According to Fajan's rule, degree of covalency (ionic potential), ϕ polarisation power of the cation charge on the cation.
1size of the cation
Alkaline earth metals contains bipostive (H2+) ions in their compounds.
So, here
(i) Charge on cation, i.e. + 2 is constant.
(ii) Halide present (X) is also constant.
So, the covalent character depends on the size of alkaline earth metal. As we move down the group, size of metal ion increases.
Be2+<Mg2+<Ca2+<Sr2+<Ba2+
So, Be2+ readily forms covalent compounds like BeX2, because of very high positive charge density over its small size, so that it readily polarises anionic spherical electron cloud.

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