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Question

The d-electron configurations of Mn2+,Fe2+,Co3+,andNi2+ are 3d5,3d6,3d6,3d8, respectively, Which of the following aqua complexes will exhibit the minimum paramagnetic behavior ?

A
[Fe(H2O)6]2+
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B
[Co(H2O)6]2+
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C
[Ni(H2O)6]2+
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D
[Mn(H2O)6]2+
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Solution

The correct option is C [Ni(H2O)6]2+
Option (C) is correct.
(A) : [Fe(H2O)6]2+ has 4 unpaired electrons.
(B): [Co(H2O)6]2+ has 4 unpaired electrons.
(C) : [Ni(H2O)6]2+ has 2 unpaired electrons.
(D) : [Mn(H2O)6]2+ has 5 unpaired electrons.
Thus [Ni(H2O)6]2+ will exhibit the minimum paramagnetic behaviour.

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