The decreasing basic order of the following compounds is: i.NH3ii.PH3iii.AsH3iv.SbH3
A
(i)>(ii)>(iii)>(iv)
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B
(iv)>(iii)>(ii)>(i)
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C
(ii)>(i)>(iii)>(iv)
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D
(ii)>(i)>(iv)>(iii)
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Solution
The correct option is A(i)>(ii)>(iii)>(iv) The basic character of hydrides of 15 group decreases down the periodic table because size increases down the group and LP ¯¯¯e density decreases. NH3>PH3>AsH3>SbH3