The decreasing nucleophilic order of the following compounds is: i.⊖CNii.⊖OHiii.⊖OMeiv.⊖CH3v.H⊖
A
(v)>(iv)>(iii)>(ii)>(i)
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B
(i)>(ii)>(iii)>(iv)>(v)
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C
(iv)>(v)>(ii)>(iii)>(i)
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D
(i)>(ii)>(iii)>(v)>(iv)
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Solution
The correct option is D(iv)>(v)>(ii)>(iii)>(i) Different nucleophilic centres in ⊖CN,H⊖,⊖CH3, but all belong to the same period. Basic and nucleophilic orders are same.