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Question

The decreasing order of basic nature in the following is:
i. Pyrrole ii. Pyridine iii. Aniline

A
ii>iii>i
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B
ii>i>iii
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C
iii>ii>i
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D
iii>i>ii
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Solution

The correct option is A ii>iii>i
Pyridine>Aniline>Pyrrole (diagram shown)
In (I), lone pair of N is not in delocalisation of π¯e.
In (II) and (III), lone pair of N is used in deloalisation of π¯e.
But in (III), LP¯es on N are involved in aromaticity, so it is less basic than (II).
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