The decreasing order of basic nature in the following is: i. Pyrrole ii. Pyridine iii. Aniline
A
ii>iii>i
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B
ii>i>iii
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C
iii>ii>i
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D
iii>i>ii
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Solution
The correct option is A ii>iii>i Pyridine>Aniline>Pyrrole (diagram shown) In (I), lone pair of N is not in delocalisation of π¯e. In (II) and (III), lone pair of N is used in deloalisation of π¯e. But in (III), LP¯e′s on N are involved in aromaticity, so it is less basic than (II).