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Question

The decreasing order of nucleophilicities of the following is :

I:Me3CH
II:Me2NH
III:MeOH
IV:HBr

A
(I)>(II)>(III)>(IV)
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B
(IV)>(III)>(II)>(I)
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C
(IV)>(III)>(I)>(II)
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D
(II)>(l)>(III)>(IV)
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Solution

The correct option is B (IV)>(III)>(II)>(I)
Acidity : HBr>MeOH>Me2NH>Me3CH
Basicity and nucleophilicity:
Br<MeO<Me2N<Me3C
i.e., (IV)>(llI)>(II)>(I)

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