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Question

The decreasing order of reactivity of following compound towards OH−ions is:
(I) 3-nitrobromobenzene
(II) 2, 4, 6-trinitrobromobenzene
(III) 4-nitrobromobenzene
(IV) 2, 4-dinitrobromobenzene

A
I > II > III > IV
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B
II > IV > III > I
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C
IV > II > III > I
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D
II > IV > I > III
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Solution

The correct option is B II > IV > III > I
Greater the number of NO2, groups at ortho and para positions to Br group, greater is the reactivity of the compound towards OH ions due to stabilization of intermediate carbanion. (II) having three NO2 groups is most reactive while (I) having NO2 group at meta position is least reactive.
Hence the reactivity order is II > IV > III > I

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