The decreasing order of reactivity of following compound towards OH−ions is:
(I) 3-nitrobromobenzene
(II) 2, 4, 6-trinitrobromobenzene
(III) 4-nitrobromobenzene
(IV) 2, 4-dinitrobromobenzene
A
I > II > III > IV
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B
II > IV > III > I
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C
IV > II > III > I
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D
II > IV > I > III
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Solution
The correct option is B II > IV > III > I Greater the number of −NO2, groups at ortho and para positions to −Br group, greater is the reactivity of the compound towards OH− ions due to stabilization of intermediate carbanion. (II) having three −NO2 groups is most reactive while (I) having −NO2 group at meta position is least reactive.
Hence the reactivity order is II > IV > III > I