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Question

The degeneracy of the H-atom in a shell is 9. The value of the principal quantumn number for the shell is?

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Solution

First of all yes there is only 1 e- present in atom of H. But here the atom is "hydrogen like" which can be He+, Li+2 Be3+, etc. The question was twisted at the point n=3, when it said n=3 then the atom can be "hydrogen like" as I mentioned above.

Now n=3 makes the above orbitals with 3s, 3p, 3d and 3f. Now (l) quantum number for 3s=0 for 3p=1, for 3d=2 and for 3f=3.

Now, electron can jump in case of 3s=0 to 1, 3p=0 to 3, 3d= 0 to 5 and 3d= 0 to 7

Thus, we can say that from above orbitals, there will be degeneration in all of them


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