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Question

The degree of ionization of a 0.1M bromoacetic acid solution is 0.132. Calculate the pH of the solution and the pKa of bromoacetic acid.

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Solution

Degree of ionization, α=0.132
Concentration, c = 0.1 M
Thus, the concentration of H3O+=c.α
=0.1×0.132=0.0132pH=log[H+]=log(0.0132)=1.879(or)1.88
Now,
Ka=Cα2=0.1×(0.132)2Ka=.0017pKa=2.75


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