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Question

The ΔfH for CO2(g),CO(g)andH2O(g) are 393.5,110.5 and 241.8kJmol1 respectively. The standard enthalpy change (in kJ) for the reaction is:


CO2(g)+H2(g)CO(g)+H2O(g)

A
524.1
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B
41.2
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C
-262.5
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D
-41.2
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Solution

The correct option is C 41.2
First write the balanced chemical reactions for the formation of carbon dioxide, carbon monoxide and water.

C+O2CO2;ΔH=393.5kJ ... (i)

C+12O2CO;ΔH=110.5kJ ...(ii)

H2+12O2H2O;ΔH=241.8kJ ...(iii)

Then obtain the required equation by equating (ii)+(iii)(i):

CO2+H2CO+H2O;ΔH=+41.2

Hence, the standard enthalpy change for the reaction is 41.2 kJ/mol.

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