Vant Hoff's Equation and Effect of Temperature on Equilibrium Constant
The Δ H f ∘ f...
Question
The ΔH∘f for CO2(g), CO(g) and H2O(g) are - 393.5, -110.5 and - 241.8 KJ mol−1 respectively. The standard enthalpy change (in kJ) for the reaction CO2+H2→CO+H2O is:
A
524.1
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B
41.2
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C
-262.5
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D
-41.2
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Solution
The correct option is B 41.2 Given C+O2→CO2; ΔH∘=−393.5kJ ....(i) C+12O2→CO; ΔH∘=−110.5kJ ....(ii) H2+12O2→H2O; ΔH∘=−241.8kJ ....(iii) By Eqs. (ii) + (iii) - (i) CO2+H2→CO+H2O; ΔH∘=41.2