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Question

The dissociation energy of CH4 and C2H6 are respectively 360 and 620 kcal/mol. The bond energy of C−C bond is:

A
260 kcal/mol
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B
180 kcal/mol
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C
130 kcal/mol
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D
80 kcal/mol
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Solution

The correct option is B 80 kcal/mol

The given that

Bond dissociation enthalpy of CH4=360 is the energy required to break 4 CH bonds in it.

Thus dissociation enthalpy of 1 CH

Bond disssociation enthalpy of CH44=3604=90 kcal/ mol.

Bond dissociation enthalpy of C2H6=620 is the energy required to break 6 CH bonds in it.

1 CH bonds.

Thus, Bond dissociation enthalpy for CC = Bond dissociation enthalpy for C2H6 6 (Bond dissociation enthalpy for 1CH)

6206(90)=620540

80 kcal/ mol.

This is the required solution.

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