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Question

The dissociation energy of CH4(g) is 360 kcal mol−1 and that of C2H6(g) is 620 kcal mol−1. The C−Cbond energy

A
260 kcal mol1
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B
180 kcal mol1
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C
130 kcal mol1
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D
80 kcal mol1
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Solution

The correct option is D 80 kcal mol1
Let the bond dissociation energy of CC and CH bond be x kcal/mol and y kcal/mol respectively.
So, for methane molecule 4y=360
y=90 kcal/mol
For ethane molecule, x+6y=620
x+540=620
x=80 kcal/mol
Option D

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