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Question

The dissociation of nitrogen pentoxideis a first order reaction. In first 24 min. 75% of nitrogen pentoxide is dissociated. What amount of nitrogen pentoxidewill be left behind after one hour of start of reaction?

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Solution

Dear ​Hardee Shah,

For 1st order reactionk=2.303tlogaa-xwhere; k=rate constantt=time (in min)a=initial conc.a-x=final conc.k=2.30324log10.25=0.058 min-1so after 1 hr or 60 min amount of N2O5 left is (a-x)0.058=2.30360log1a-xlog1a-x=1.511a-x=101.51=32.36a-x=132.36=0.031 or 3.1% of N2O5 will be left after 60 min. Regards

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