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Byju's Answer
Standard XII
Chemistry
Polyhalogen Compounds
The distillat...
Question
The distillation of bleaching powder and acetone gives:
A
C
H
C
l
3
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B
chloral
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C
C
H
3
C
l
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D
C
C
l
4
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Solution
The correct option is
A
C
H
C
l
3
The distillation of bleaching powder and acetone gives chloroform
C
H
C
l
3
Bleaching powder
C
a
O
C
l
2
supplies the necessary chlorine and slaked lime (calcium hydroxide) for the reaction.
C
a
O
C
l
2
+
H
2
O
→
C
a
(
O
H
)
2
+
C
l
2
Chlorine so obtained acts as a mild oxidizing as well as chlorinating agent.
Chlorination of acetone gives trichloroacetone.
C
H
3
C
O
C
H
3
+
3
C
l
2
→
C
C
l
3
C
O
C
H
3
+
3
H
C
l
Hydrolysis of trichloroacetate gives chloroform.
2
C
C
l
3
C
O
C
H
3
+
C
a
(
O
H
)
2
→
2
C
H
C
l
3
+
(
C
H
3
C
O
O
)
2
C
a
Suggest Corrections
0
Similar questions
Q.
The formula of chlorinated acetone produced in the distillation of acetone with bleaching powder is:
Q.
The product obtained when bleaching powder is distilled with acetone:
Q.
Acetone is mixed with bleaching powder to give:
Q.
Regarding dipole moment of the following species.
C
H
4
,
C
H
3
C
l
,
C
H
2
C
l
2
,
C
H
C
l
3
,
C
C
l
4
Zero :
C
C
l
4
Maximum :
C
H
3
C
l
Order being :
C
H
4
=
C
C
l
4
<
C
H
C
l
3
<
C
H
2
C
l
2
<
C
H
3
C
l
If true enter 1, else enter 0.
Q.
Arrange the following in the
decreasing dipole moment :
C
H
3
C
l
,
C
H
2
C
l
2
,
C
H
C
l
3
,
C
C
l
4
is:
C
H
3
C
l
>
C
H
2
C
l
2
>
C
H
C
l
3
>
C
C
l
4
.
if true enter 1, else enter 0.
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