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Question

The drain cleaner, Drainex contains small bits of aluminum which react with caustic soda to produce dihydrogen. What volume of dihydrogen at 20C and one bar will be released when 0.15 g of aluminum reacts?

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Solution

The balanced chemical equation is 2Al+2NaOH+2H2O2NaAlO2+3H2.
54 g (2 mol) of Al will give 3 moles (or 67.2 L) of hydrogen.
0.15 g of Al will give 67.254×0.15=0.189L of hydrogen.
The volume of hydrogen is at 1 bar and 273 K. The volume at 1 bar and 200C will be, V=PVTPT=1×0.189×2931×273=0.2028L=202.8 ml.

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