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Question

The EAN of Fe atom in (CO)3Fe(CO)3Fe(CO)3 is :

A
34
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B
35
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C
36
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D
37
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Solution

The correct option is C 36
The effective atomic number of Fe in (CO)3Fe(CO)3Fe(CO)3 is 26+3(2)+3(1)+1=36
The atomic number of Fe is 26.

3 CO ligands are terminal and donate 2 electron to Fe.

3 CO ligands are bridged and donate 1 electron to Fe.

There is one Fe-Fe bond which contributes 1 electron.

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