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Question

The EAN of nickel in Ni(CO)4 is:

A
36
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B
38
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C
28
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D
454
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Solution

The correct option is A 36
EAN rule:-
The total number of es linked with the central metal atom or ion in a complex plus the es donated by the ligand is known as Effective Atomic Number, i.e; EAN. It is the attainment of noble gas configuration.
EAN=Zx+2nL
Z= atomic number of the metal in the complex ion.
x= oxidation state of the central metal atom.
n= no. of ligands.
L= no. of coordinate bond formed by the ligand.

[Ni(CO)4](EAN)=[280+2×4×1]
=28+8
=36.

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