The edge lengths of the unit cell in terms of the radius of spheres constituting fcc, bcc and simple cubic unit cell are respectively:
In FCC: The atoms at the face diagonals touch each. If a is the edge length of cube and r is the radius of the atom.
So, √2a=4r
⇒a=2√2r
In bcc: The atoms at the body diagonal touch each other.
So, √3a=4r
⇒a=4√3r
In simple cubic: The atoms at the corners touch each other.
So, a=2r