The efficiency of a cell with cell reaction under standard conditions: A(s)+B2+(aq)⇌A2+(aq)+B(s);ΔH=−285kJ is 85%. The standard electrode potential for the cell is:
A
1.20V
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B
2.40V
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C
1.10V
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D
1.26V
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Solution
The correct option is D1.26V Thermodynamic efficiency is given by the ratio of the Gibb's function change to the enthalpy change in the overall cell reaction. Efficiency =−ΔGoΔHo=nEoFΔHo=85100 ∴Eo=85×285×1000100×2×96500=1.26