The electrode potentials for : Cu2+(aq)+e−→Cu+(aq) and Cu+(aq)+e−→Cu(s) are +0.15V and +0.50V respectively. The value of E∘Cu2+/Cu will be:
Cu2++1e−→Cu+ ; E01=0.15V,ΔG01=−n1E01F
Cu++1e−→Cu ; E02=0.50V,ΔG02=−n2E02F
Cu2++2e−→Cu ; ΔG∘=ΔG∘1+ΔG∘2
i.e.(−2)nE∘F=(−1)n1E∘1F+(−1)n2E∘2F
E∘=n1ΔE∘1+n2ΔE∘2n=0.15×1+0.50×12=0.325V