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Secondary Cells

The electrode...

Question

The electrode reactions for charging of a lead battery are:
$P b S O_{4} + 2 e \to P b + S O_{4}^{2 -}$
$P b S O_{4} + 2 H_{2} O \to P b O_{2} + S O_{4}^{2 -} + 4 H + 2 e$
The electrolyte in the battery is an aqueous solution of $H_{2} 3 O_{4}$ . After this battery has been charged:

A

The sulphuric acid will be more concentrated

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B

The sulphuric acid will be less concentrated

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C

The concentration of 1.1 M will be unchanged

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D

H_{2} S O_{4}

will have been completely decomposed

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Solution

The correct option is B The sulphuric acid will be more concentrated
In the process of charging of lade storage battery we provide electron then again lade started to attach with electron and formation of sulfuric acid is started in electrolyte solution.
So we can say that after this battery has been charged the sulfuric acid will be more concentrated.

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Similar questions

Q. During the discharge of a lead storage battery, the density of sulphuric acid fell from 1.294 to 1.139

g m L^{- 1}

H_{2} S O_{4}

1.294 g m L^{- 1}

is 39% and that of density

1.139 g m L^{- 1}

is 20% by weight.The battery holds 3.5 L of acid and the volume practically remains constant during discharge. The number of ampere hours for which the battery must have been used are........................
The discharging and charging reactions are:

P b + S O_{4}^{2 -} \to P b S O_{4} + 2 e^{-}

P b O_{2} + 4 H^{+} + S O_{4}^{2 -} + 2 e^{-} \to P b S O_{4} + 2 H_{2} O

Q. During the discharge of a lead storage battery, the density of sulphuric acid fell from

1.294

1.139 g m l^{- 1}

. Sulphuric acid of density

1.294 g m l^{- 1}

is 39% by weight and that of density

1.139 g m l^{- 1}

is 20% by weight. The battery holds 3.5 L of the acid and the volume remained practically constant during the discharge. Find the number of ampere-hours for which the battery must has been used.

The charging and discharging reactions are as follows:

$P b + S O_{4}^{2 -} \to P b S O_{4} + 2 e^{-}$ (charging)

$P b O_{2} + 4 H^{\oplus} + S O_{4}^{2 -} + 2 e^{-} \to P b S O_{4} + 2 H_{2} O$ (discharging)

During the discharge of a lead storage battery, the density of sulphuric acid fell from $1.294$ to $1.139$ gm $L^{- 1}$ . Sulphuric acid of density $1.294$ gm $L^{- 1}$ is $39$ % by weight and that of density 1.139 gm $L^{- 1}$ is $20$ % by weight. The battery holds $3.5$ litres of acid and the column practically remained constant during the discharge.

Calculate the number of ampere-hours for which the battery must have been used. The charging and discharging reactions are :

$P b + S O {_{4}}^{2 -} \to P b S O_{4} + 2 e^{-}$ (charging)

$P b O_{2} + 4 H^{+} + S O {_{4}}^{2 -} + 2 e^{-} \to P b S O_{4} + 2 H_{2} O$ (discharging)

Q. During the discharge of a lead storage battery the density of sulphuric acid fell from

1.294

1.139 {g mL}^{- 1}

H_{2} S O_{4}

1.294 {g mL}^{- 1}

is 39% and that of density

1.139 {g mL}^{- 1}

is 20% by weight. The battery holds

3.5 L

of acid and the volume practically remains constant during the discharge. Calculate the number of Ampere hours for which the battery must have been used. The discharging reactions are:

P b + S O_{4}^{2 -} \to P b S O_{4} + 2 e^{-} (anode)

P b O_{2} + 4 H^{+} + S O_{4}^{2 -} + 2 e^{-} \to P b S O_{4} + 2 H_{2} O (cathode)

Q. During the discharge of a lead storage battery, the density of sulphuric acid fell from 1.294 to 1.139 g

m l^{- 1}

and sulphuric acid of the density of 1.294 g

m l^{- 1}

is 39% by mass and that of the density of 1.139 g

m l^{- 1}

is 20% by mass. The battery holds 3.5 litre of acid and the volume practically remained constant during the discharge. Calculate the no. of ampere hour for which the battery must have been used. The charging and discharging reactions are:

P b + S O_{4}^{2 -} \to P b S O_{4} + 2 e ⟹

P b O_{2} + 4 H^{+} + S O_{4}^{2 -} + 2 e \to P b S O_{4} + 2 H_{2} O ⟹

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