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Question

The electronic configuration 1s2,2s2,2p6,3s2,3p6,3d9 represents a:

A
metal atom
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B
non-metal atom
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C
non-metallic anion
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D
metallic cation
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Solution

The correct option is D metallic cation
In the given electronic configuration, total no. of electrons = 27.
For a neutral atom having 27e⁻ the electronic configuration will be:
1s², 2s², 2p, 3s², 3p, 4s², 3d⁷.
Thus, it is not a neutral metal or non-metal atom.

We know that, 4s is filled before 3d according to the electronic configuration series. But in the given configuration, 4s orbital is empty and electrons are present in 3d which clearly indicates that electrons have been removed.
Thus, it represents a cation and not an anion.

Electronic configuration of Cu (29e⁻) : 1s², 2s², 2p, 3s², 3p, 4s¹, 3d¹
Electronic configuration of Cu²⁺ cation (removing 2 e⁻ from Cu) :1s², 2s², 2p, 3s², 3p, 3d

Hence, the given electronic configuration represents a metallic cation (Cu²⁺) .


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