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Question

The electronic configuration of carbon is 1s22s22p2. There are 12 electrons in C2. The correct electronic configuration of C2 molecule is:

A
(σ1s2)(σ1s2)(σ2s2)(σ2s2)(σ2p2z)(π2p2x)
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B
(σ1s2)(σ1s2)(σ2s2)(σ2s2)(π2p2x=π2p2y)
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C
(σ1s2)(σ1s2)(σ2s2)(σ2s2)(σ2p2z)(π2p1x=π2p1y)
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D
(σ1s2)(σ1s2)(σ2s2)(σ2s2)(π2p2x=π2p1y)
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Solution

The correct option is B (σ1s2)(σ1s2)(σ2s2)(σ2s2)(π2p2x=π2p2y)
Because C2 is diamagnetic compound and
C2(12e)=σ1s2σ1s2σ2s2σ2s2π2px2=π2p2y
It does not contain any unpaired electrons.

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