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Question

The electronic configuration of Cu2+ ion is :

A
[Ar]3d84s1
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B
[Ar]3d94s0
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C
[Ar]3d74s2
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D
[Ar]3d84s0
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Solution

The correct option is B [Ar]3d94s0
Correct Electron Configuration for Copper (Cu)

Half-filled and fully filled subshell have got extra stability. Therefore, one of the 4s2 electrons jumps to the 3d9. This give us the (correct) configuration of:

1s22s22p63s23p63d104s1

For the Cu+ ion we remove one electron from 4s1 leaving us with: 1s22s22p63s23p63d10

For the Cu2+ ion we remove a total of two electrons (one from the 4s1 and one form the $3d^{10}) leaving us with

1s22s22p63s23p63d9

Cu2+=[Ar]4s03d9

Hence, the correct option is B

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