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Question

The electronic configuration with maximum exchange energy will be

A
3d1xy 3d1yz 3d1zx 4s1
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B
3d1xy 3d1yz 3d1zx 3d1x2y2 3d2z24s2
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C
3d2xy 3d2yz 3d2zx 3d2x2y2 3d1z24s1
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D
3d2xy 3d2yz 3d2zx 3d2x2y2 3d2z24s1
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Solution

The correct option is D 3d2xy 3d2yz 3d2zx 3d2x2y2 3d2z24s1
When two electrons with the same spin are present in the degenerate orbitals of a subshell. These electrons tend to exchange their positions and the energy released due to this exchange is called exchange energy.
The number of exchanges is maximium when the orbitals are half- filled or full- filled.


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