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Question

The electrons identified by quantum numbers n and l:
(A) n=4, l=1
(B) n=4, l=0
(C) n=3, l=2
(D) n=3, l=1
can be placed in order of increasing energy as:

A
(C) < (D) < (B) < (A)
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B
(D) < (B) < (C) < (A)
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C
(B) < (D) < (A) < (C)
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D
(A) < (C) < (B) < (D)
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Solution

The correct option is B (D) < (B) < (C) < (A)
From the quantum numbers, the orbitals are
(a) 4p (b) 4s (c) 3d (d) 3p
According to Bohr Bury's n+l rule, increasing order of energy (D) < (B) < (C) < (A)
Note: If the two orbitals have same value of (n+l) then the orbital with lower value of n will be filled first.

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