The correct option is A K
K(19)=1s22s22p63s23p64s1
Mg(12)=1s22s22p63s2
Ca(20)=1s22s22p63s23p64s2
Sc(21)=1s22s22p63s23p63d14s2
Here, K has the least first ionisation energy among the given options since it is easier to remove an electron from 4s1.
Also, K has the highest second ionization among the given options since it is very difficult to remove an electron from
2p6
So, here K has the highest difference between first and second ionization energy.