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Question

The element having greatest difference between its first and second ionisation energy is:

A
K
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B
Ca
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C
Mg
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D
Sc
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Solution

The correct option is A K
K(19)=1s22s22p63s23p64s1
Mg(12)=1s22s22p63s2
Ca(20)=1s22s22p63s23p64s2
Sc(21)=1s22s22p63s23p63d14s2
Here, K has the least first ionisation energy among the given options since it is easier to remove an electron from 4s1.
Also, K has the highest second ionization among the given options since it is very difficult to remove an electron from
2p6
So, here K has the highest difference between first and second ionization energy.

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