The correct option is B P
Valence electrons are the electrons present in the outermost shell.
Electronic configuration of the given element is:
Na: 1s22s22p63s1P: 1s22s22p63s23p3Si: 1s22s22p63s23p2Al: 1s22s22p63s23p1
Thus, phosphorous has the maximum number of valence electrons, i.e., 5.