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Question

The elements of s-block group 1A that produce superoxides have

A

High electronegativity

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B
High ionization energy
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C

High polarizability

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D

Low ionization potential

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Solution

The correct option is D

Low ionization potential


A simple recall of potassium superoxide's properties can help answer this question. Of the given options the first three are not applicable . These elements are highly electropositive, that is they tend to lose the valence shell electron easily. The only major exception here is Lithium which has a high ionization enthalpy (first). But Lithium does not easily form superoxide. O2 is a large anion. The superoxides of K, Rb and Cs are stable as these cations can stabilize the large O2 anion. So option d) Low ionization potential


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