The emf of a concentration cell consisting of two zinc electrode, one dipping into M/4 solution of zinc sulphate and the other into M/16 solution of the same salt at 250C :
A
0.0125 V
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B
0.0250 V
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C
0.0178 V
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D
0.0356 V
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Solution
The correct option is C 0.0178 V For the given cell, the standard cell potential, E0cell=0.0V.
The emf of the cell is Ecell=E0cell−0.05922log(M16)(M4)=0.0V+0.0296log4=0.0178V.