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Byju's Answer
Standard XII
Chemistry
Nernst Equation
The emf of ce...
Question
The emf of cell at 298 K is:
[Given :
2.303
×
R
T
F
=
0.06
]
A
1.07 V
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B
1.04 V
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C
1.03 V
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D
1.06 V
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Solution
The correct option is
A
1.07 V
According to Nernst equation,
E
c
e
l
l
=
E
0
c
e
l
l
−
0.06
n
l
o
g
[
Z
n
2
+
]
[
C
u
+
+
]
n
=
2
=
1.1
−
0.06
×
1
2
=
1.1
−
0.03
=
1.07
V.
Thus, the correct option is
A
Suggest Corrections
0
Similar questions
Q.
Given the equilibrium constant,
K
c
of the reaction :
C
u
(
s
)
+
2
A
g
+
(
a
q
)
→
C
u
2
+
(
a
q
)
+
2
A
g
(
s
)
is
10
×
10
15
, calculate the
E
o
c
e
l
l
of this reaction at
298
K
[
2.303
R
T
F
a
t
298
K
=
0.059
V
]
Q.
EMF of the following cell is
0.634
v
o
l
t
at
298
K
P
t
|
H
2
(
1
a
t
m
)
|
H
+
(
a
q
)
|
|
H
g
2
+
2
(
a
q
.
1
N
)
|
H
g
(
l
)
. The pH of anode compartment is :
(Given,
E
o
H
g
2
+
2
|
H
g
=
0.28
and
2.303
R
T
F
=
0.059
)
Q.
At 298 K, the standard reduce potentials are 1.51 V for
M
n
O
−
4
, 1.36 V for
C
l
2
|
C
l
−
, 1.07 V for
B
r
2
|
B
r
−
, 0.54 V for
I
2
|
I
−
. At
p
H
=
3
, permangnate is expected to oxidize
:
(
R
T
F
=
0.059
)
Q.
The solubility product
(
K
s
p
m
o
l
3
d
m
−
9
)
of
M
X
2
at 298 K based on the information available for the given concentration cell is (take
2.303
×
R
×
298
/
F
=
0.059
V
):
Q.
EMF of the cell,
A
g
|
A
g
N
O
3
(
0.1
M
)
|
K
B
r
(
1
N
)
,
A
g
B
r
(
s
)
|
A
g
is
−
0.6
V
at
298
K
Calculate the
K
s
p
of
A
g
B
r
at
298
K
.
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