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Question

The EMF of cell Ni|Ni2+||Au3+|Au is:
Given that E=0.25V for Ni2+|Ni;E=1.5V for Au3+|Au

A
1.25V
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B
-1.25V
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C
1.75V
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D
2.0V
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Solution

The correct option is C 1.75V
Ecell=EcathodeEanode
Cathode here is Au as Au3+Au
i.e., reduction at Au electrode
and as NiNi2+ i.e., oxidation at Ni electrode, it is anode.
So,
Ecell=1.5(0.25)
=1.75V

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