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Standard XII
Chemistry
Standard Electrode Potentials
The emf of th...
Question
The emf of the cell in which the following reaction,
Z
n
(
s
)
+
N
i
2
+
(
0.1
M
)
→
Z
n
2
+
(
1.0
M
)
+
N
i
(
s
)
occurs, is found to be
0.5105
V
at
298
K
. The standard emf of the cell is:
A
0.4810
V
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B
0.5696
V
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C
−
0.5105
V
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D
0.5400
V
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Solution
The correct option is
D
0.5400
V
E
c
e
l
l
=
E
0
−
0.059
n
log
Q
;
E
0
=
s
t
a
n
d
a
r
d
e
m
f
Z
n
(
s
)
+
N
i
2
+
(
0.1
M
)
→
Z
n
2
+
(
1.0
M
)
+
N
i
(
s
)
n
=
2
For the reaction,
0.5105
=
E
0
−
0.059
2
log
[
1.0
]
[
0.1
]
E
0
=
0.5105
+
0.059
2
log
10
E
0
=
0.5105
+
0.0295
=
0.54
V
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0
Similar questions
Q.
The e.m.f. of the cell involving following changes,
Z
n
(
s
)
+
N
i
2
+
(
1
M
)
→
Z
n
2
+
(
1
M
)
+
N
i
(
s
)
is
0.5105
V
.
The standard e.m.f. of the cell is:
Q.
Determine the standard emf of the cell and standard free energy change of the cell reaction.
Z
n
/
Z
n
2
+
∥
N
i
2
+
/
N
E
o
Z
n
2
+
/
Z
n
=
−
0.76
V
E
o
N
i
2
+
/
N
i
=
−
0.25
V
Q.
Determine the standard emf of the cell and standard free energy change of the cell reaction
Z
n
|
Z
n
2
+
|
|
N
i
2
+
|
N
i
. The standard reduction potentials of
Z
n
2
+
|
Z
n
and
N
i
2
+
|
N
i
half cells are
−
0.76
V
and
−
0.25
V
respectively.
Q.
The standard emf for the given cell reaction,
Z
n
+
C
u
2
+
⟶
C
u
+
Z
n
2
+
is
1.10
V
at
25
o
C
. The emf for the cell reaction, when
0.1
M
C
u
2
+
and
0.1
M
Z
n
2
+
solutions are used at
25
o
C
is:
Q.
At temperature of 298K, the emf of the following electrochemical cell will be:
A
g
(
s
)
|
A
g
+
(
0.1
M
)
|
|
Z
n
2
+
(
0.1
M
)
|
Z
n
(
s
)
(Given,
E
o
c
e
l
l
=
−
1.562
V
)
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