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Question

The empirical formula of a monobasic acid is CH2O.The vapour density of its ester is 44. Mlecular formula of the acid?

A
C2H4O2
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B
CH2O2
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C
C2H2O2
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D
C3H6O3
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Solution

The correct option is A C2H4O2
Given the vapour density of ester= 44
So molecular weight of ester= 44×2=88
Given, empirical formula of acid= (CH2O); weight= 30
Molecular formula of acid= (CH2O)n; weight= n×30
C2H4O2n=2
Because the ester formed CH2OH|
CH2OH

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