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Question

The energies of activation forA2+B22AB are 180kJ mol1 forward and 200kJ mol1 reverse reactions respectively. The presence of catalyst lowers the activation energies of both (forward and reverse) reactions (A2+B22AB) by 100kJ mol1. The magnitude of enthalpy change of the reaction in the presence of catalyst will be (in kJ mol1):

A
300
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B
120
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C
20
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D
20
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Solution

The correct option is C 20
Presence of catalyst lowers the activation energy of both forward & backward reaction by equal amounts :
Hence, it does not cause any change in enthalpy of a reaction.
ΔH=EfEb
=200180=20kJ/mol
This is the value of enthalpy change with and without the catalyst.
Option C is correct.

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