The correct option is D Sample X is undoped while samples Y and Z have been doped with a fifth group and a third group impurity respectively
When a pentavalent impurity is added to a semiconductor, it is called a donor impurity because it donates an electron which occupies a discrete energy level(shown by broken lines) just below the condition band, as in sample Y. Trivalent impurity, on the other hand, is called an acceptor impurity because the impurity atoms introduce unoccupied discrete energy levels just above the valence band, as in sample Z.