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Question

The energy band diagrams for three semiconductor samples of silicon are as shown. We can then assert that,

A
Sample X is undoped while samples Y and Z have been doped with a third group and a fifth group impurity respectively.
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B
Sample X is undoped while both samples Y and Z have been doped with a fifth group impurity.
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C
Sample X has been doped with equal smounts of third and fifth group impurities while sample Y and Z are undoped.
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D
Sample X is undoped while samples Y and Z have been doped with a fifth group and a third group impurity respectively.
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Solution

The correct option is D Sample X is undoped while samples Y and Z have been doped with a fifth group and a third group impurity respectively.
There is no extra energy level in between conduction and valence bands, in sample X. Clearly, it is an intrinsic silicon, i.e. undoped silocon.

In sample Y, the extra energy level lies near the bottom of the conduction band, so it is a Ntype semiconductor and has been doped with an element from the fifth group.

In sample Z, the extra energy level lies near the top of the valence band, so it is a Ptype semiconductor and has been doped with an element from the third group.

Hence, (D) is the correct answer.

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