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Question

The energy required to vapourise one mole of benzene at it's boiling point is 31.2 kJ/mol. For how long a 100W electric heater has to be operated in order to vaporize a 100g sample of benzene at it's boiling temperature?

A
743 sec
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B
400 sec
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C
3.9×104 sec
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D
371 sec
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Solution

The correct option is A 400 sec
Boiling point is a temperature at which the vapour pressure of liquid equals atmospheric pressure.
Energy required to vapourise one mole of benzene is 31.2 KJ/mole.
Mole of benzene = 100 gm
Molar mass of benzene = 78 g/mole
Moles of given benzene sample = 10078
Energy required to vapourise 10078 mole of benzene = 31.2×10078KJ
Power is Energy per unit time.
Power of heater = 100W
Time required = 31.2×100×100078×100
= 400sec


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